The S4 intake should fit the heads, but will just make everything else more complicated. No reason to use it over the S6/S8, which bolts right up (except the TB, which may be a different size depending on the year of your A6)
The 40v v8 exhaust manifold flanges are available from advanced automotion for $189. Go wild!
JHM could probably make you up a set of headers, as they had some in the past. However, I am not sure if they are still available.