Sadly the part is toast. Once the membrane is torn/ripped then it is worthless. If the membrane isn’t damaged then you can clean out the PCV with brake cleaner or carb cleaner just like the B6/7 S4 guys have done. The part is not cheap so it would be a good idea to clean out the PCV with every carbon clean.
I am going through a similar issue with a B8 S5 right now too. Later on I will start a separate thread because this car has been a journey to fix.
The membrane of the PCV valve/oil separator was torn like yours. There was oil inside the PCV valve.
http://i284.photobucket.com/albums/ll37/Jimmybones777/SAM_1247_zpszmegufto.jpg
http://i284.photobucket.com/albums/ll37/Jimmybones777/SAM_1246_zps6dzwsmrm.jpg
I did a carbon clean first before replacing the PCV valve. The valves looked similar to RS4 carbon clean pictures that I posted your engine out thread.
http://i284.photobucket.com/albums/ll37/Jimmybones777/pre%20carbon%20clean%20cylinder%205_zpsrac3jzdt.jpg
http://i284.photobucket.com/albums/ll37/Jimmybones777/Post%20carbon%20clean%20cylinder%204_zpsukx3hbjs.jpg
Under two hundred miles after the carbon clean and before replacing the PCV valve, the intake valves and ports looked like this. The oil being sucked in caused other issues too.
http://i284.photobucket.com/albums/ll37/Jimmybones777/SAM_1242_zpsqq8lkmwt.jpg
The 4.2 FSI V8s and the 5.2 FSI V10s are very similar in a lot of ways so it would be a good idea of the V10 S6/S8 guys follow along with the FSI V8 guys threads. I have been reading the clean your injectors thread by komseh and that should apply to the V10s also.
http://audirevolution.net/forum/index.php?topic=3731.0